退火时间对Al-Mg-Mn-Zr-Er合金冷轧板组织与性能的影响

    Effects of Annealing Time on Microstructure and Properties of Al-Mg-Mn-Zr-Er Alloy Cold Rolled Sheet

    • 摘要: 制备了Al-4.5Mg-0.7Mn-0.2Zr-0.2Er合金冷轧板材,在板材再结晶温度下退火不同时间获得不同程度再结晶的板材,测试不同程度再结晶的板材的力学性能和腐蚀稳定性,并采用金相显微镜、TEM、EBSD对合金显微形貌进行分析。结果表明:冷轧合金在275℃退火45 min时,得到最优的力学性能和腐蚀性能的匹配。随着再结晶程度的增加,冷轧合金内部原有的连续晶界被破坏,β相由沿晶界连续分布变为断续分布,合金的腐蚀性能增加。合金中复合添加Er和Zr,形成细小弥散的Al3(Er,Zr)质点,可钉扎晶界阻碍晶界的迁移,抑制合金的再结晶,提高再结晶温度。

       

      Abstract: The cold rolled Al-4.5Mg-0.7Mn-0.2Zr-0.2Er alloy sheet was prepared. After annealing at different recrystallization temperatures, the plates with different degrees of recrystallization were obtained. The mechanical properties and corrosion stability of the recrystallized sheet were tested and the microstructure of the alloy was analyzed by metallographic microscope, TEM and EBSD. The results show that, when the cold rolled alloy is annealed at 275 ℃for 45 min, the optimum match of mechanical properties and corrosion properties is obtained. With the increase of recrystallization degree, the original continuous grain boundary in cold rolled alloy is destroyed, and the β phase changes from continuous distribution along grain boundary to intermittent distribution, and the corrosion resistance of the alloy increases. The addition of Er and Zr in the alloy can form fine dispersed Al3(Er, Zr) particles, which can block the migration of grain boundary, inhibit the recrystallization of the alloy and raise the recrystallization temperature.

       

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