超声功率比对AZ31B镁合金微弧氧化复合陶瓷层耐蚀性能的影响

    Effect of Ultrasonic Power Ratio on Corrosion Resistance of AZ31B Magnesium Alloy Micro-arc Oxide Composite Ceramic Layer

    • 摘要: 为改善镁合金微弧氧化膜层的组织结构与耐蚀性能,在含Al2O3粉末微粒的铝酸盐-磷酸盐复合电解液体系中,应用超声波辅助微弧氧化技术在AZ31B镁合金表面制备复合陶瓷层,研究超声功率比对微弧氧化陶瓷层的影响。采用扫描电镜(SEM)观察MAO膜层的微观形貌,采用X射线衍射(XRD)分析MAO膜层的物相组成,并采用电化学极化法测定MAO膜层在电解液中的腐蚀行为。试验结果发现,在超声功率比为60%时,制备的微弧氧化复合陶瓷层表面孔隙较少,膜层厚度最大,出现了更多的MgAl2O4相,表现出最好的耐蚀性,腐蚀速率减小至1.05 mg·m-2·h-1

       

      Abstract: In order to improve the structure and corrosion resistance of the magnesium alloy micro-arc oxidation coating,in the aluminate-phosphate composite electrolyte system containing Al2O3 powder particles, a composite ceramic layer was prepared on the surface of AZ31B magnesium alloy by using ultrasonic assisted micro-arc oxidation technology to study the effect of ultrasonic power ratio on the micro-arc oxidation ceramic layer. The microscopic morphology of the MAO film layer was observed by scanning electron microscopy(SEM). The phase composition of the MAO film layer was analyzed by X-ray diffraction(XRD), and the corrosion behavior of the MAO film layer in the electrolyte was measured by electrochemical polarization. The experimental results find that at the ultrasonic power ratio of 60%, the surface pores of the prepared micro-arc oxidation composite ceramic layer are less, the film thickness is the largest, and more MgAl2O4 phases appear,which shows the best corrosion resistance and the corrosion rate decreases to 1.05 mg·m-2·h-1.

       

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