塔河油田某油井管件在H2S/CO2/高矿化度耦合环境失效分析

    Failure Analysis on Oil Well Pipe in Tahe Oilfield under H2S/CO2/High Salinity Coupling Environment

    • 摘要: 油井面临的腐蚀环境随着油气田的深度开发而愈发复杂,研究管材在复杂环境中的失效机理对保证油田安全平稳生产具有重要意义。结合理化性质测试、有限元分析以及SEM、EDS及XRD等研究了塔河油田某油井管件在H2S/CO2/高矿化度耦合环境中的失效机理。结果表明:管材的理化性质均符合标准。由于过渡区产生的应力集中造成了应力腐蚀开裂的风险,而H2S、CO2、Cl-以及水垢覆盖层引起了局部腐蚀并产生了大量H+,H+向腐蚀孔隙深处的渗透造成了腐蚀前端的脆化,在应力作用下腐蚀微裂纹拓展导致开裂。失效形式属于局部腐蚀与应力腐蚀的耦合机制。在此类工况下,对工作的管件应注意合理的结构设计以及定期加注缓蚀阻垢剂,避免类似失效的再次发生。

       

      Abstract: The corrosion environment of oil wells becomes more and more complicated with the deep development of oil and gas fields. It is of great significance to clarify the failure mechanism of pipe materials in complex corrosion environments to ensure the safe and stable production of oil fields.The failure mechanism of an oil well pipe in Tahe Oilfield with the coupling corrosion environment of H2S/CO2/high salinity was studied by combining physical and chemical properties testing,finite element analysis and SEM, EDS and XRD. The results show that the physical and chemical properties of the pipe meet the standard, but the stress concentration generates in the transition zone causing the risk of stress corrosion cracking. The H2S,CO2, Cl- and scale coating cause local corrosion and produce a large amount of H+. The penetration of H+ into the depth of the corrosion holes cause the embrittlement of the corrosion front. The expand of the corrosion microcracks cause the cracking under the effect of stress. The failure mechanism belongs to the coupling mechanism of local corrosion and stress corrosion.Pipes working under such conditions should pay attention to reasonable structural design and regularly add corrosion and scale inhibitors to avoid the recurrence of similar failures.

       

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