基于正交综合平衡法的CoCrFeMnNi高熵合金等离子熔覆工艺参数优化

    Optimization of Plasma Cladding Process Parameters of CoCrFeMnNi High Entropy Alloy Based on Orthogonal Comprehensive Balance Method

    • 摘要: 采用正交试验优化了等离子熔覆工艺参数,并在Q235钢基体上制备了CoCrFeMnNi高熵合金涂层。利用XRD、SEM、EDS以及显微硬度计等分析优化后熔覆层组织和性能特征。结果表明,工艺参数对熔覆层稀释率影响程度依次为熔覆速度、弧电流和送粉气流量,对熔覆层显微硬度影响程度依次为弧电流、熔覆速度和送粉气流量。综合极差和熔覆层宏观形貌分析,得到最优工艺参数组合为:弧电流70 A,熔覆速度7 mm/s,送粉气流量8 L/s。在此工艺条件下,熔覆层表面无裂纹,熔覆表层主元素分布均匀,物相主要由类Ni型简单结构的FCC相组成;熔覆层稀释率为17.86%,熔覆层表面显微硬度分布比较均匀,而截面显微硬度受组织结构影响呈梯度变化。

       

      Abstract: The parameters of plasma cladding technology (PCT)were optimized by orthogonal tests, and the CoCrFeMnNi high entropy alloy coating was prepared by PCT on Q235 steel substrate.The microstructure and properties of cladding layer after optimization were analyzed by means of X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive spectroscopy (EDS) and microhardness tester.The results show that the significance influence of plasma cladding process parameters on the dilution ratio of cladding layer is in turn with the cladding speed, arc current and feeding gas flow, but which on the microhardness of cladding layer is in turn with the arc current, cladding speed and feeding gas flow.The optimal parameter combination obtained by the polar difference and macromorphology of cladding layer is arc current of 70 A, cladding speed of 7 mm/s, feeding gas of 8 L/s.Under these conditions, the cladding layer is crack-free, the main elements are uniformly distributed in the cladding layer surface, and the cladding layer is only composed of FCC structure phase as the type of Ni.The dilution ratio of the cladding layer is about 17.86%.The hardness distribution on the cladding layer surface is relatively uniform, while the microhardness of the cross section varies with gradient under the influence of microstructure.

       

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