哈斯勒合金Ni50Mn35In15-xSix的磁热效应和相变研究

    Research on Magnetocaloric Effect and Phase Transformation of Ni50Mn35In15-xSix Heusler Alloy

    • 摘要: 使用熔体快淬法制备了Ni50Mn35In15-xSix合金样品,使用综合物性测量系统PPMS对样品进行磁性测量;对样品的磁热效应和晶体结构进行了分析。结果表明:Ni50Mn35In15-xSix哈斯勒合金随着Si掺杂的增大,对合金内部的磁矩产生影响,低温段磁化发生变化,(Tc1/2逐渐减小。在(Tc1/2处发生的磁相变导致了磁熵较大变化,同时相变温度区间较宽,取得了高的制冷量。5 T的外加磁场下,x=0.8时,在316.6 K时得到最大的制冷量187.92 J/kg,此时的磁熵变达到5.63 J/kg。

       

      Abstract: Ni50Mn35In15-xSix alloy samples were prepared by melt quenching method, and the magnetic properties were measured by using PPMS, then the magnetocaloric effect and crystal structure of the samples were analyzed. The results show that with the increase of Si doping Ni50Mn35In15-xSix, Heusler alloy has an impact on the internal magnetic moment of the alloy,the magnetization at low temperature changes, (Tc1/2 gradually decreases. The magnetic phase change at (Tc1/2 causes a large change of magnetic entropy, and the wide temperature range of the phase change makes it possible to obtain a high refrigerant capacity. Under the applied magnetic field of 5 T, when x=0.8, at 316.6 K, the maximum refrigerant capacity reaches 187.92 J/kg at this time,and the magnetic entropy change is 5.63 J/kg.

       

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