微观组织对Ti-0.2Pd钛板材耐腐蚀性的影响

    Effect of Microstructure on Corrosion Resistance of Ti-0.2Pd Titanium Sheet

    • 摘要: 在工业纯钛中加入0.2%钯制备的Ti-0.2Pd钛合金具有优异的耐腐蚀性,但是其结构件在实际应用中仍存在缝隙腐蚀或点蚀现象。研究了结构件用板材轧制面、横截面和纵截面的微观结构及耐腐蚀性能,并分析了微观组织和晶体学取向对板材耐腐蚀性能的影响。结果表明:具有基面织构轧制面的自腐蚀电流密度最小,腐蚀速率最低,容抗弧半径最大,极化电阻最高,耐腐性最优。横截面耐腐蚀性能次之,纵截面最差。

       

      Abstract: Ti-0.2Pd titanium alloy prepared by adding 0.2% palladium into industrial pure titanium, has excellent corrosion resistance. But there is still crevice corrosion or pitting corrosion in its structural parts in practical application.The microstructure and corrosion resistance of the rolling surface, cross section and longitudinal section of the alloy sheet were studied. The effects of grain morphology and crystallographic orientation on the corrosion resistance were analyzed. The results show that the rolling surface with basal texture has the smallest self corrosion current density, the lowest corrosion rate,the largest capacitive arc radius, the highest polarization resistance and the best corrosion resistance. The corrosion resistance of the cross section is second, followed by longitudinal section.

       

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