TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层的抗氧化性能和耐磨性能

    Oxidation Resistance and Wear Resistance of TiAlN-TiAlN/CrSiAlN-TiAlON Multilayer Coatings

    • 摘要: 采用电弧离子镀技术在TiCN基金属陶瓷基体上制备了TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层和TiAlN单层涂层,并对两种涂层的结构、抗氧化性能、硬度和摩擦磨损性能进行对比分析。结果表明,TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层组织致密,各子层之间界面过渡自然,结合紧密。多层涂层的抗氧化性能优于TiAlN单层涂层的,在900℃保温1h后,TiAlN涂层组织彻底被破坏,涂层组织全部转变成疏松多孔结构,而TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层仅在表层和内层与基体的界面位置产生形成了疏松多孔组织,中间层和内层大部分仍较完整。相比于TiAlN单层涂层,TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层具有更高的硬度。在干摩擦条件下,TiAlN-TiAlN/CrSiAlN-TiAlON多层涂层摩擦系数低,耐磨性好,多层涂层的磨损机制主要为氧化磨损,TiAlN单层涂层的磨损机制主要为磨粒磨损和氧化磨损。

       

      Abstract: TiAlN-TiAlN/CrSiAlN-TiAlON multilayer coating and TiAlN single layer coating were prepared on Ti CN cermet substrate by arc ion plating, and the structure, oxidation resistance, hardness and friction and wear properties of the two coatings were compared and analyzed. The results show that the structure of TiAlN-TiAlN/CrSiAlN-TiAlON multilayer coating is compact, and transite natural between the sublayers. The oxidation resistance of TiAlN-TiAlN/CrSiAlN-TiAlON multilayer coating is excellent than that of TiAlN single layer coating. After heat preservation at 900 ℃ for 1 h, the microstructure of TiAlN coating is completely destroyed, and the structure of coating is completely transformed into a loose porous structure. The TiAlN-TiAlN/CrSiAlN-TiAlON multilayer coating only forms a loose porous structure at the interface between the outer layer and the substrate, and most of the middle layer and the inner layer are still relatively intact. Compared with TiAlN single-layer coating, TiAlN-TiAlN/CrSiAlN-TiAlON multi-layer coating has higher hardness. Under the condition of dry friction, the friction coefficient of TiAlN-TiAlN/CrSiAlN-TiAlON multilayer coating is low and the wear resistance is excellent. The wear mechanism of the multilayer coating is mainly oxidation wear, while the wear mechanism of TiAlN single layer coating is mainly abrasive wear and oxidation wear.

       

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