电流密度对超临界纳米复合镀层微观结构与性能的影响

    Effects of Current Density on Microstructure and Properties of Supercritical Nanocomposite Coatings

    • 摘要: 以具有独特性能的石墨烯量子点作为第二相添加物,采用超临界脉冲电沉积技术制备Ni基纳米复合镀层,探究超临界条件下电流密度对镀层的微观结构、耐腐蚀性和力学性能的影响。结果表明:电流密度为6 A·dm-2时,所制备镀层的微观结构呈均匀化和致密化,且呈现出更好的球状度。拉曼光谱检测显示,超临界脉冲电沉积可以提高石墨烯量子点的质量。当电流密度为6 A·dm-2时,所制备镀层的耐腐蚀性和力学性能更为优异,其容抗弧半径最大,容抗模量最大,腐蚀电流密度最小,腐蚀电流密度仅为3、4.5和9 A·dm-2时所制备镀层的52%、62%和29%;其显微硬度最高,达837.6 HV0.2,摩擦系数和磨痕截面积均最小,展现出最为优异的耐磨性。

       

      Abstract: Using graphene quantum dots with unique properties as the second phase additive, Ni-based nanocomposite coatings were prepared by supercritical pulse electrodeposition technology. The effects of current density on the microstructure, corrosion resistance and mechanical properties of coatings under supercritical conditions were investigated.The results show that when the current density is 6 A·dm-2, the microstructure of the prepared coating is uniform and densified, and it shows better sphericity. Raman spectroscopy detection shows that supercritical pulsed electrodeposition can improve the quality of graphene quantum dots. When the current density is 6 A·dm-2, the corrosion resistance and mechanical properties of the prepared coating are more excellent, its capacitive arc radius is the largest, the capacitive modulus is the largest, and the corrosion current density is smallest. Its corrosion current density is only 52%, 62% and 29% of the coatings prepared at current densities of 3, 4.5 and 9 A·dm-2. Its microhardness is the highest, reaching 837.6 HV0.2, and the friction coefficient and wear scar cross-sectional area are the smallest, showing the best wear resistance.

       

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