热处理温度对磁控溅射氧化钇薄膜形貌及物相的影响

    Effects of Heat Treatment Temperature on Morphology and Phase of Magnetron Sputtering Yttrium Oxide Film

    • 摘要: 采用射频磁控溅射方法在短钨纤维表面制备Y2O3薄膜,薄膜厚度约100 nm。为便于研究,首先采用相同工艺将Y2O3薄膜沉积在钨片上,分别在500、700及900℃热处理1 h,通过扫描电镜、XRD射线衍射手段对薄膜表面形貌及物相变化分析,确定用于镀Y2O3薄膜短钨纤维的热处理温度。结果表明,700、900℃的薄膜均发生破损,而500℃热处理后的薄膜表面完整,相比于未热处理薄膜,结晶度提高。在此基础上,对镀Y2O3薄膜短钨纤维进行500℃热处理,最终在短钨纤维表面制备出了均匀完整、结晶度良好的Y2O3薄膜,为后续W_f/W复合材料制备奠定了工艺基础。

       

      Abstract: Y2O3film was prepared on the surface of short tungsten fibers by radio frequency magnetron sputtering.The film thickness is about 100 nm.For convenience of study,firstly,the Y2O3film was deposited on the tungsten sheets by the same process,and it was heat-treated at 500℃,700℃and 900℃for 1 h,respectively,the surface morphology and phase of the film were analyzed by SEM and XRD,and the heat treatment temperature of short tungsten fiber coated with Y2O3film was determined.The results show that the films at 700℃and 900℃are all damaged,while the surface of the film is intact after heat treatment at 500℃,and the crystallinity of the film is improved compared with that of the unheat-treated film.On this basis,the short tungsten fiber coated with Y2O3film is heat-treated at 500℃,finally,Y2O3film with uniformity,integrity and good crystallinity is prepared on the surface of short tungsten fibers,which can lay a technological foundation for the subsequent preparation of Wf/W composites.

       

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