大气等离子喷涂制备的不同结构热障涂层抗CMAS腐蚀性能

    Comparison of CMAS Corrosion Resistance of Different Structure Thermal Barrier Coatings Prepared by Atmospheric Plasma Spraying

    • 摘要: 通过大气等离子喷涂技术(APS)分别制备了具有垂直裂纹的致密结构热障涂层(DVC TBC)和嵌入式团聚颗粒结构热障涂层(EMAP TBC),比较了在1300℃条件下的熔融钙镁铝硅酸盐(CMAS)在两种涂层中渗透行为以及1100℃条件下涂层抗热震性能差异。结果表明,喷涂态EMAP涂层呈现疏松多孔结构,经CMAS渗透后渗透区域均匀且明显;喷涂态DVC涂层结构致密且存在垂直裂纹,CMAS在涂层各个区域呈现不均匀渗透特征,在致密区CMAS浓度含量比EMAP涂层少,但垂直裂纹使得CMAS渗透到了比EMAP涂层更深的位置。此外,EMAP涂层的抗热震性能优于DVC涂层。该结果为未来热障涂层的微观结构和抗CMAS腐蚀性能改进提供了基础。

       

      Abstract: Dense vertical cracks thermal barrier coating(DVC TBC) and embedded micro-agglomerated particle thermal barrier coating(EMAP TBC) were prepared by atmospheric plasma spraying(APS). The penetration behavior of molten calcium-magnesium-alumina-silicates(CMAS) at 1300 ℃ and the thermal shock performance at 1100 ℃ were compared between the two coatings. The results show that the EMAP TBC has a loose porous structure, and the penetration area of CMAS is uniform and obvious; the structure of DVC TBC is dense and vertical cracks exist, and the penetration of CMAS is uneven. In the dense area, the concentration of CMAS is less than that of EMAP coating, but the vertical crack makes CMAS penetrate deeper than that of EMAP coating. In addition, the thermal shock performance of EMAP TBC is better than that of DVC TBC. The results provide a basis for improving the microstructure and CMAS corrosion resistance of thermal barrier coatings in the future.

       

    /

    返回文章
    返回