碳纳米管增强空心微点阵材料的制备及其压缩性能

    Preparation of Carbon Nanotube Reinforced Hollow Microlattice Materials and Its Compression Properties

    • 摘要: 结合聚合物投影微立体光刻增材制造技术、碳纳米管镍磷纳米化学镀复合镀层制备工艺以及化学刻蚀法制备了一种碳纳米管碳纳米管增强空心微点阵材料,开展了原位压缩试验,并对其力学性能进行了分析。通过对空心微点阵材料开展原位压缩试验发现,在镀层中加入3.08wt%的碳纳米管,可使空心微点阵材料的弹性模量提高2.4~2.6倍、压缩强度提高2.0~2.9倍。应用剪切滞后模型和Halpin-Tsai模型,对碳纳米管的强化效应进行了细观力学分析,发现碳纳米管对材料的力学强化效应主要是由碳纳米管和镍磷非晶相的相互作用引起的剪切滞后效应和剪切带阻滞效应。研究方法和成果对于提高空心微点阵材料的力学性能强化乃至其工程应用,具有重要的现实意义。

       

      Abstract: A carbon nanotube carbon nanotube reinforced hollow microlattice material was prepared by combining polymer projection micro-stereolithography additive manufacturing technology, carbon nanotube nickel phosphorus nanoelectroless electroless plating composite coating preparation process and chemical etching method. Compression test was carried out and its mechanical properties were analyzed. Through the in-situ compression test of the hollow micro-lattice material, it is found that adding 3.08 wt% carbon nanotubes to the coating can increase the elastic modulus of the hollow micro-lattice material by 2.4-2.6 times and the compressive strength by 2.0-2.9 times. Using the shear lag model and the Halpin-Tsai model, the reinforcement effect of carbon nanotubes was analyzed micromechanically, it is found that the mechanical reinforcement effect of CNTs on materials is mainly the shear hysteresis effect and shear band retardation effect caused by the interaction between CNTs and nickel-P amorphous phase. The research methods and results have important practical significance for improving the mechanical properties of hollow microdot matrix material and even its engineering application.

       

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