O2对超高速激光熔覆431M2涂层在CO2水相中耐腐蚀性的影响

    Influence of O2 on Corrosion Resistance of Ultra-High Speed Laser Cladding 431M2 Coatings in CO2 Aqueous Phase

    • 摘要: 在利用CO2驱油时,O2作为注入CO2流中常见杂质,会影响管道材料的耐腐蚀性。为了解腐蚀各阶段O2杂质对含缺陷不锈钢涂层的影响,本文利用循环动电位极化、恒电位极化测试和长周期EIS测试,研究了在pH3条件下,O2对超高速激光熔覆431M2涂层在饱和CO2溶液中耐腐蚀性能的影响。结果表明,当431M2涂层处于钝化时,O2的存在促进了钝化膜的生长,涂层保护性得到提高,但是亚稳态点蚀的萌生变多。当431M2涂层处于稳态点蚀时,O2的存在会促进局部腐蚀凹坑的发展。长周期EIS实验表明,O2杂质在腐蚀前期有助于涂层钝化膜的生长,但随着浸泡时间的推移,一旦在缺陷处发生稳态点蚀,O2杂质会加速点蚀的发展,降低涂层的耐腐蚀性。

       

      Abstract: O2 impurities, as common impurities in CO2 streams, can affect the corrosion resistance of pipeline materials during CO2 oil drive. In order to understand the effect of O2 impurities on stainless steel coatings containing defects at various stages of corrosion, this paper investigates the effect of O2 on the corrosion resistance of ultra-high speed laser cladding 431M2 coatings in saturated CO2 solution at pH3 using cyclic dynamic potential polarization, constant potential polarization tests and long cycle EIS tests. The results show that when the 431M2 coating is in the passivation zone, the presence of O2 promotes the growth of the passive film and the coating protection performance is improved, but the sprouting of sub-steady state pitting becomes more. When the 431M2 coating is in steady-state pitting, the presence of O2 promotes the development of local corrosion pits. Long-period EIS experiments show that O2 impurities contribute to the growth of the coating passive film in the pre-corrosion stage, but with immersion time, once steady-state pitting occurs at the defect, O2 impurities accelerate the occurrence of pitting and reduce the corrosion resistance of the coating.

       

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