AlCl3对HT700合金材料在硝酸熔盐中腐蚀行为的影响

    Effect of AlCl3 on Corrosion Behavior of HT700 Alloy Material in Nitrate Molten Salt

    • 摘要: 为了降低合金在熔盐中的腐蚀速率,研究了AlCl3 对镍铁基HT700 合金在Hitec 熔盐中电化学腐蚀性能的影响。结果表明,1wt%AlCl3 的添加量,Al3+的积极作用和Cl-的消极作用相互影响、相互抵消,以及添加的Al 元素太少,不足以与合金内部Al 元素形成浓度梯度进而向内扩散保护基体,没有达到预想的效果,后期可以进一步提高硝酸盐中AlCl3 的浓度,或者选用其它不含Al 元素的合金进一步验证AlCl3 的作用。

       

      Abstract: In order to reduce the corrosion rate of the alloy in the molten salt, the effect of AlCl3 on the electrochemical corrosion properties of a nickel-iron-based HT700 alloy in the Hitec molten salt was investigated.The results show that the amount of 1wt%AlCl3, the positive effect of Al3+and the negative effect of Cl-affects and offsets each other, and the addition of Al element is too little, not enough to form a concentration gradient with alloy internal Al element inward diffusion to protect the matrix, does not achieve the desired effect.Later can further improve the concentration of AlCl3 in nitrate, or choose other alloys without Al element to further verify the role of AlCl3.

       

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