钛合金微弧氧化陶瓷膜层物理性能和防腐性能研究

    Study on Physical Properties and Corrosion Resistance of Titanium Alloy Micro-arc Oxidation Ceramic Coatings

    • 摘要: 选择TC4钛合金材料作为基体,针对其表面处理利用微弧氧化技术构建陶瓷膜层,从而可以提高钛合金的物理性能和防腐性能。以硅酸钠、六偏磷酸钠、氟化钠溶液作为电解液,在钛合金表面制备出微弧氧化膜层。借助SEM和XRD研究了微弧氧化膜层形貌和结构组成,对膜层进行硬度、厚度、结合力、绝缘性及疲劳强度等物理性能试验,并通过盐雾腐蚀试验、湿热试验和海水浸泡试验分析了其防腐性能。结果表明,钛合金微弧氧化膜的抗腐蚀能力不仅取决于自身物相结构、内部致密性,还取决于氧化膜的厚度、相组成及结构上的缺陷等。

       

      Abstract: TC4 titanium alloy was selected as the substrate, and micro arc oxidation technology was used to build ceramic coatings for its surface treatment, which can improve the physical properties and anti-corrosion properties of titanium alloy.Taking sodium silicate, sodium hexametaphosphate and sodium fluoride solutions as electrolytes, the micro arc oxidation coatings were prepared on the surface of titanium alloys. By using SEM and XRD, the surface morphology and structural composition of the micro arc oxidation film were studied. The physical properties such as hardness, thickness, adhesion,insulation and fatigue strength of the film were tested, the anticorrosion properties were analyzed by salt spray corrosion test,moisture heat test and seawater immersion test. The results indicate that the corrosion resistance of titanium alloy micro arc oxidation film depends not only on its own phase structure and internal density, but also on the thickness, phase composition and structural defects of the oxide film.

       

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