Y掺杂对TiAl-Nb合金组织与耐热腐蚀性能的影响

    Influence of Yttrium Doping on Microstructure and Hot Corrosion Resistance of TiAl-Nb Alloy

    • 摘要: 采用真空电弧非自耗熔炼方法制备Ti45Al-8Nb-m Y(m=0,0.1,0.3和0.6at%)合金,研究了Y掺杂对合金组织和耐高温热腐蚀性能的影响。结果表明:添加微量Y不会明显改变Ti Al-Nb合金的主要相组成,但能够有效细化合金组织并抑制合金中孔洞等缺陷形成。高温热腐蚀试验结果表明,添加微量Y能有效改善Ti Al-Nb合金的耐热腐蚀性能,其中Y含量为0.3at%时合金腐蚀产物剥落最轻微且腐蚀产物层最为致密,其机制在于Y有效细化了合金α2+γ片层组织、提高了γ相的含量,有利于提高Al2O3在热腐蚀产物中的含量并促进形成连续的保护性Al2O3中间层,抑制了O、S、Cl等腐蚀介质的内扩散。

       

      Abstract: Ti45Al-8Nb-m Y(m =0, 0.1, 0.3 and 0.6at%) alloys were prepared by vacuum arc non-consumable melting method. The influence of Y doping on the microstructure and high temperature hot corrosion resistance of the alloys were studied. The results show that doping of minor Y can not significantly change the main phase composition of Ti Al-Nb alloy,but can effectively refine the microstructure of the alloy and inhibit the formation of defects such as pores in the alloy. The high temperature hot corrosion test reveals that doping of minor Y in Ti Al-Nb alloys effectively improves its high-temperature corrosion resistance. Among the investigated Y concentrations, the alloy with 0.3at% Y exhibits the least severe corrosion product delamination and the most dense corrosion product layer. The improvement can be attributed to the effective refinement of the α2+γ lamellar microstructure and the increase of the γ phase content by Y doping. These factors facilitate an increase of Al2O3content in the corrosion products and promote the formation of a continuous protective Al2O3intermediate layer, which inhibits the internal diffusion of corrosive media such as O, S and Cl.

       

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