Ce对2.8%Si-0.8%Al无取向硅钢夹杂物变质的影响

    Effect of Ce on Modification of Inclusions in 2.8% Si-0.8% Al Non-oriented Silicon Steel

    • 摘要: 采用向2.8%Si-0.8%Al无取向硅钢中添加单一稀土Ce的方法,研究不同Ce含量对试验钢中夹杂物变质的影响。依据Thermo-Calc热力学计算和吉布斯自由能计算,判断钢液中可能生成的夹杂物种类,并分析各种夹杂物存在的稳定性和相互转化条件。在此基础上,借助扫描电镜及能谱仪等检测手段,对试验钢中典型夹杂物的种类、尺寸以及形貌进行表征与分析。Thermo-Calc热力学计算和吉布斯自由能计算表明,稀土Ce的添加能够调控无取向硅钢中的析出相,增加了夹杂物的种类并促进其类型的转变。添加稀土Ce后,试验钢中均能够生成Ce2O2S,并且其含量逐渐增加,而MnS的含量逐渐减少。结果显示,随着稀土Ce含量的增加,试验钢中夹杂物的种类发生了明显变化,从最初的MnS、Al N、Al2O3、Al2O3-Al N、Al N-MnS夹杂物,逐步改性为Ce2O2S、CeAlO3、Ce2O2S-MnS、Ce-O-Al-S、Ce2O2S-Al N稀土夹杂物,形貌从原来的不规则形状逐渐转变为更加规则的球状。

       

      Abstract: The effects of different Ce contents on the modification of inclusions in 2.8%Si-0.8%Al non-oriented silicon steel were studied by adding single rare earth Ce. According to Thermo-Calc thermodynamic calculation and Gibbs free energy calculation, the types of inclusions that may be generated in molten steel were judged, and the stability and mutual transformation conditions of various inclusions were analyzed. On this basis, the types, sizes and morphologies of typical inclusions in the test steel were characterized and analyzed by means of scanning electron microscopy and energy dispersive spectroscopy. Thermo-Calc thermodynamic calculation and Gibbs free energy calculation show that the addition of rare earth Ce can regulate the precipitated phase in non-oriented silicon steel, increase the type of inclusions and promote the transformation of their types. After adding rare earth Ce, Ce2O2S can be generated in the test steel, and its content gradually increases, while the content of MnS gradually decreases. The results show that with the increase of rare earth Ce content, the types of inclusions in the test steel have changed significantly. From the initial MnS, Al N, Al2O3, Al2O3-Al N, Al N-MnS inclusions, gradually modified to Ce2O2S, CeAlO3, Ce2O2S-MnS, Ce-O-Al-S, Ce2O2S-Al N rare earth inclusions, the morphology gradually changes from the original irregular shape to a more regular spherical shape.

       

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