Al纳米颗粒掺杂对Sn基复合焊点组织与性能影响的研究

    Effect of Al Nanoparticles Doping on Microstructure and Properties of Sn-based Composite Solder Joints

    • 摘要: 研究了微量Al纳米颗粒(0~0.5wt%)掺杂对三维封装技术中芯片堆叠互连Sn基焊点的界面组织、润湿性能以及剪切强度的影响。结果表明,掺杂微量的Al纳米颗粒可以显著抑制Sn基复合焊点界面层金属间化合物的生长。当Al颗粒掺杂量为0.3wt%时,Sn/Cu焊点界面层厚度由最初始的3.00μm下降到2.28μm。当Al纳米颗粒掺杂量超过0.3wt%时,复合焊点界面层厚度却出现增厚的趋势。此外,随着微量Al颗粒的掺杂,钎料的熔点未出现明显变化,Sn基钎料的润湿角得到降低。当Al纳米颗粒的掺杂量为0.3wt%时,Sn基钎料的润湿角由未掺杂的16.8°下降到13.4°,降幅20.2%。Sn-0.3Al复合焊点的剪切性能则达到了最大值16.9 MPa,增幅24.3%。继续增加Al纳米颗粒掺杂量,复合焊点的润湿性能和剪切强度逐渐下降。

       

      Abstract: The effects of doped Al nanoparticles(0-0.5wt%) on the interfacial structure, wettability and shear strength of Sn-based solder joints used for chip stacking interconnect in 3D packaging technology were investigated. The results show that the doped Al nanoparticles can significantly inhibit the growth of intermetallic compounds at the interface layer of Sn-based solder joints. When the doping amount of Al particles is 0.3wt%, the thickness of the interfacial layer decreases from the initial of 3.00 μm to 2.28 μm. However, when the doping amount of Al nanoparticles exceeds 0.3wt%, the thickness of the interface layer of the composite solder joint increases. In addition, with the doping of trace Al particles, the melting point of the solder does not change significantly, and the wetting angle of the Sn-based solder decreases. When the doping amount of Al nanoparticles is 0.3wt%, the wetting angle of Sn-based solder decreases from the initial without doping of 16.8° to 13.4°, a decrease of 20.2%. For Sn-0.3Al composite solder joint, the shear strength reaches the maximum value of 16.9 MPa, an increase of 24.3%. However, the wettability and shear strength of the composite solder joints decrease gradually with the increase of Al nanoparticle doping amount.

       

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