银溶胶对AZ31B镁合金微弧氧化膜耐蚀性能的影响研究

    Effects of Ag Sol on Properties of Micro-Arc Oxidation Coatings Formed on Magnesium Alloy

    • 摘要: 为进一步提高镁合金微弧氧化膜的耐蚀性和抗菌性能,在硅酸盐体系电解液中添加通过调整AgNO3用量而获得的A和B两种银溶胶,采用TT260数字式涡流测厚仪、SEM、XRD和XPS研究银溶胶对膜层厚度、微观形貌、物相及元素组成、元素化学结合状态的影响。同时采用电化学工作站和平板菌落计数法检测膜层的耐蚀性和抗菌性能。结果表明,微弧氧化电解液中添加银溶胶,一定程度上增加了膜层厚度,减小了膜层微孔孔径和微孔数量,并向膜层中引入了Ag2O2物相,使膜层的耐蚀性和抗菌性能均得到增强。当制备银溶胶时所用的AgNO3的量为0.2 mol/L,获得的银溶胶(B溶胶)的添加量为5vol%时,膜层的耐蚀性最佳,较镁合金基体和未添加的分别提高了近4个和2个数量级,比等量的A溶胶(AgNO3用量为0.1 mol/L)的增加了48.7%。

       

      Abstract: To further improve the corrosion resistance and antibacterial property of micro-arc oxidation(MAO) coating prepared on magnesium alloy, two kinds of silver sols of A and B prepared by adjusting the amount of AgNO3 was added into the silicate-based electrolyte. The effects of silver sol on coating thickness, microstructure, phase and element composition as well as chemical bonding state of elements were studied by TT260 digital eddy current thickness gauge, SEM, XRD and XPS. At the same time, the corrosion resistance and antibacterial property of the coating were measured by electrochemical workstation and plate colony counting method. The results show that adding silver sol into MAO electrolyte increases the thickness of the coating, and reduces the the size and number of micropores in the coating to some extent, simultaneously introduces Ag2O2 into the coating, which enhance the corrosion resistance and antibacterial property of the coating. Moreover, when the amount of AgNO3 used in the preparation of silver sol is 0.2 mol/L and the addition amount of the obtained silver sol (B sol) is 5vol%, the corrosion resistance of the coating is the best, which is nearly 4 and 2 orders of magnitude higher than that of magnesium alloy substrate and coating produced in the electrolyte without silver sol, and is 48.7% higher than that of the same amount of A sol (0.1 mol/L AgNO3).

       

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