ZL114A合金Sb-Te联合变质技术研究

    Research on Sb-Te Combined Modification Technology of ZL114A Alloy

    • 摘要: 以QJ3185—2003《航天用铝合金ZL205A、ZL114A铸件规范》中ZL114A合金为研究对象,利用试验探讨了Sb与Te的加入量以及静置时间对ZL114A合金T6热处理态组织和力学性能的影响。结果表明:Sb-Te联合变质过程中,Te能够在铝液中较快溶解,发挥其变质作用。Sb因熔点较高,完全在铝液中溶解则需要较长的时间,且溶解后的Sb要完全发挥其变质作用,还需要一定的孕育期。当Sb和Te含量分别为0.25%和0.15%,静置45 min时,变质效果达到最佳,α枝晶与共晶体分布均匀,共晶硅为颗粒状,合金的力学性能达到峰值;当静置时间延长至90 min时,变质效果没有出现衰退现象,Sb-Te联合变质具有长效性。但当Te的加入量为0.20%时,相比最优变质效果,共晶硅颗粒状变少,短杆状共晶硅变长变粗,合金力学性能降低。

       

      Abstract: Taking ZL114A alloy in QJ3185—2003 《Specifications for Aluminum Alloys ZL205A and ZL114A Castings for Aerospace》 as research object, the effects of the addition amounts of Sb and Te and standing time on the microstructure and mechanical properties of ZL114A alloy in T6 heat treatment state were investigated by experiments. The results show that during the Sb-Te joint modification process, Te can dissolve quickly in molten aluminum and exert its modification role. Due to its high melting point, it takes a long time for Sb to completely dissolve in molten aluminum, and a certain incubation period is needed for the dissolved Sb to fully exert its modification effect. When the contents of Sb and Te are 0.25% and 0.15%, respectively and the standing time is 45 min, the modification effect is optimal, α dendrites and eutectic are uniformly distributed, eutectic silicon is granular, and the mechanical properties of the alloy reach the peak. When the standing time is extended to 90 min, the modification effect does not decline, and the combined modification of Sb-Te has long-term effect.However, when the addition amount of Te is 0.20%, compared with the optimal modification effect, there are fewer eutectic silicon grains, short rod-shaped eutectic silicon becomes longer and thicker, and the mechanical properties of the alloy are reduced.

       

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