316L不锈钢表面CoCrFeNiMo/WC高熵合金激光熔覆层的性能研究

    Properties of CoCrFeNiMo/WC High-Entropy Alloy Laser Cladding on 316L Stainless Steel Surface

    • 摘要: 采用激光熔覆技术在316L不锈钢基体上制备了CoCrFeNiMo/WC熔覆层,借助OM、XRD、SEM、显微硬度计、往复式磨损试验机、电化学工作站以及腐蚀磨损实验机等,对熔覆层的成形质量、相结构、微观组织、显微硬度、耐磨性、耐蚀性和耐腐蚀磨损性能进行了分析。结果表明:激光熔覆过程中,CoCrFeNiMo/WCxx=0、10、20、30、40,wt%)熔覆层与基体间形成了良好的冶金结合,但随WC含量的增大,熔覆层的成形质量有所下降,且熔覆层的显微组织显著变化;由羽毛状、花瓣状枝晶(x=0wt%)转变为柱状和胞状晶(x=10wt%),并进一步形成雪花状、鱼骨状组织(x=20wt%),最终形成大量、致密的枝晶状结构(x≥30wt%),晶粒尺寸呈先减小后增大的趋势。随WC含量的增大,x≤10wt%时,熔覆层的相结构为FCC+σ相,x≥20wt%时,熔覆层中产生Fe3W3C、Co3W3C、W2C和W3C等碳化物;随WC含量的增大,熔覆层的硬度增大,磨损率降低,耐腐蚀性能呈先增大后降低的趋势。熔覆层的耐腐蚀磨损性能存在一个最佳的WC加入量(x=20wt%)。

       

      Abstract: CoCrFeNiMo-WC laser cladding layer was prepared on 316L stainless steel substrate by laser cladding technology. With the help of OM, XRD, SEM, microhardness tester, reciprocating wear tester, electrochemical workstation and corrosive wear tester, the forming quality, phase structure, microstructure, microhardness, abrasion, corrosion and corrosion and wear resistance of the cladding layer was analyzed. The results show that: during the laser cladding process,good metallurgical bonding is formed between the CoCrFeNiMo-WCx(x=0 wt%, 10 wt%, 20 wt%, 30 wt% and 40 wt%) laser cladding layer and the substrate, but the forming quality of the laser cladding layer declines with the increase of WC content;the microstructure of the laser cladding layer changes remarkably with the increase of WC content, which is transformed from feathery and petal-like dendritic crystals(x=0 wt%). The microstructure of the laser cladding layer changes significantly with the increase of WC content, from feather-like and petal-like dendrites(x=0 wt%) to columnar and cellular crystals(x=10 wt%),and further forms snowflake and fishbone organizations(x=20 wt%), and ultimately forms a large number of dense dendrites(x≥30 wt%), with a tendency to decrease and then increase grain size; with the increase of WC content, the phase structure of the fused cladding layer is FCC+σ phase for x≤10 wt%. x≥20 wt%. the carbides such as Fe3W3C, Co3W3C, W2C and W3C are generated in the cladding layer; with the increase of WC content, the hardness of the cladding layer increases, the wear rate decreases, and the corrosion resistance shows a tendency to increase first and then decrease. For the corrosion and wear resistance of the laser cladding layer,there is an optimum amount of WC added(x=20 wt%).

       

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