飞秒激光制备铝板表面的超吸水-超吸光性能分析

    Analysis on Super Water Absorption and Super Light Absorption of Aluminum Plate Surface Fabricated by Femtosecond Laser

    • 摘要: 兼具超吸水和超吸光性能的铝板可在太阳能的作用下净化海水或污水。利用飞秒激光扫描铝板表面,通过调控扫描速度改变激光器输出的能量剂量,从而制备出不同尺寸的微米级沟槽结构,并测量不同沟槽尺寸的吸水和吸光性能,探究其超吸水和超吸光机理。结果表明,所制备的沟槽结构使表面呈现反重力的超吸水能力和较强的超吸光能力,在6.272 mm/s的扫描速度下,沟槽的宽度、深度和均匀性得到优化,铝板表面呈现最高的吸水速率13.6 mm/s,光吸收率均超过91%,并对紫外光具有最好的光吸收率94.7%。超吸水是由于沟槽表面附着大量纳米粒子,使表面毛细作用增强。超吸光是由于沟槽表面的谷脊结构使入射光不断反射而被吸收,从而提高铝板对太阳光的宽带吸收性能。EDS结果表明:铝板沟槽的边缘位置氧元素与碳元素的含量高于脊部中间位置,而铝元素的含量则相对较低,这是因为其边缘更靠近激光烧蚀区域,从而氧化反应更为剧烈。

       

      Abstract: An aluminum plate exhibiting both super water absorption and super light absorption properties can effectively purify seawater or wastewater under solar irradiation. Femtosecond laser was used to scan the surface of aluminum plate, and prepare micro-groove structures with different sizes by adjusting the scanning speed. The water absorption and light absorption properties were measured, and the mechanisms of super water absorption and super light absorption were explored. The results indicate that the prepared groove structures endow the surface with anti-gravity super water absorption capability and strong super light absorption capability. At the scanning speed of 6.272 mm/s, the width, depth and uniformity of the grooves are optimized, resulting in the highest water absorption rate of 13.6 mm/s on the aluminum plate surface, the light absorbance all exceeds 91% and the best absorbance of 94.7% for ultraviolet light. The super water absorption is attributed to the enhanced surface capillarity due to the attachment of a large number of nanoparticles on the groove surface. The super light absorption is due to the continuous reflection and subsequent absorption of incident light by the ridge-valley structure of the grooves, which improves the broadband absorption performance of the surface for sunlight. The results of energy dispersive spectroscopy(EDS) show that at the edge of the groove on the aluminum plate, the contents of oxygen and carbon elements are higher than those at the middle position of the ridge, while the content of aluminum element is relatively lower. This is because the edge of the groove is closer to the laser ablation area, thus making its oxidation reaction more intense.

       

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