硫酸盐还原菌对油气田管材典型局部腐蚀作用的研究进展

    Research Progress on Effect of Sulfate Reducing Bacteria on Typical Local Corrosion of Oil and Gas Field Pipes

    • 摘要: 硫酸盐还原菌(sulfate-reducing bacteria,SRB)是油气田微生物腐蚀的主要诱因,其引发的局部腐蚀问题严重威胁管材服役安全。简述了SRB腐蚀的最新研究进展,综述了SRB腐蚀机理,重点探讨了SRB与典型局部腐蚀(点蚀、应力腐蚀、缝隙腐蚀、电偶腐蚀)间的相互作用机制。研究发现,SRB在金属表面的吸附和胞外聚合物(extracellular polymeric substances,EPS)的产生会促进生物膜的形成,加剧点蚀的萌生与扩展;SRB在缝隙内外的生长差异会增强电偶效应,加速缝隙内侧阳极区金属的溶解;SRB生物膜的不均匀生长致使局部点蚀,加速应力腐蚀裂纹的成核和扩展;SRB通过利用阳极电子促进代谢和附着会加速异种材质间的电偶腐蚀过程。本文旨在明确SRB在油气田管材局部腐蚀中的作用及其影响程度,为管材腐蚀失效形式识别与腐蚀防护提供理论基础。

       

      Abstract: Sulfate-reducing bacteria (SRB) is a primary contributor of microbiologically influenced corrosion (MIC) in oil and gas fields, with their induced localized corrosion posing severe risks to the service safety of pipeline materials. Recent advances in SRB corrosion research were briefly summarized, and the mechanistic underpinnings of SRB-mediated corrosion were reviewed, and the interaction mechanisms between SRB and typical localized corrosion forms, including pitting corrosion, stress corrosion cracking, crevice corrosion, and galvanic corrosion, were specifically examined. The investigations demonstrate that SRB adhesion on metal surfaces and the secretion of extracellular polymeric substances (EPS) facilitate biofilm formation, intensifying the initiation and propagation of pitting corrosion. The differential proliferation of SRB within and outside crevices amplifies galvanic effects, accelerates the dissolution of anodic metal regions inside crevices. Heterogeneous growth of SRB biofilms induces localized pitting, promotes the nucleation and propagation of stress corrosion cracks. Additionally, SRB accelerates galvanic corrosion between dissimilar materials by exploiting anodic electrons to enhance metabolic activity and surface adhesion. This study aims to elucidate the role and severity of SRB in localized corrosion of oil and gas pipeline materials, offering a theoretical basis for identifying corrosion failure modes and formulating targeted corrosion mitigation strategies.

       

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