结构调控下PIP法制备Cf/SiC复合材料的致密化与力学性能研究

    Study on Densification and Mechanical Properties of Cf/SiC Composites Prepared by PIP Method under Structural Regulation

    • 摘要: 基于先驱体浸渍裂解法,系统探讨预制件结构参数对碳纤维增强碳化硅基(Cf/SiC)复合材料的孔隙分布、致密化过程及力学性能的影响。通过烧结增重统计、宏观/微观孔隙形貌观察,以及压缩、弯曲性能测试,揭示复合材料烧结过程中的“初期快速增重-后期缓慢饱和”演化机制,并建立指数衰减拟合模型。结果表明:铺层数34层的试样在多轮烧结过程中表现出更高的最终增重率135%,形成均匀致密结构,显著提升了材料的承载能力;结构不合理的弯曲试样因浸渗受限导致孔隙集中,最终强度降低。本研究构建了“结构参数-浸渗/烧结-孔隙分布-力学性能”的调控机制链条,为PIP工艺优化提供了实验依据与理论支撑。

       

      Abstract: Based on the PIP method, the effects of preform structural parameters on the pore distribution, densification process and mechanical properties of carbon fiber reinforced silicon carbide(Cf/SiC) composites were systematically investigated. The evolution mechanism of "rapid weight gain at the initial stage-slow saturation at the later stage" during the sintering process of composite materials was revealed through the statistics of sintering weight gain, macro/micro pore morphology observation and compression-bending property tests, and the exponential decay fitting model was established. The results indicate that the 34-layer specimens demonstrate significantly higher final weight gain rates(135%) during multiple sintering cycles, forming a homogeneous and dense structure that substantially enhanced the material's load-bearing capacity. In contrast, unreasonably structured bending specimens exhibit concentrated porosity due to infiltration limitations, resulting in reduced ultimate strength. This study establishes a comprehensive regulatory mechanism chain of structural parameters- infiltration/sintering-pore distribution-mechanical properties, providing both experimental evidence and theoretical support for PIP process optimization.

       

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