退火对V0.3CoCr1.2NiTi1.1Al0.2 EHEA微观结构和力学性能的影响

    Effect of Annealing on Microstructure and Mechanical Properties of V0.3CoCr1.2NiTi1.1Al0.2 EHEA

    • 摘要: 探究了V0.3CoCr1.2NiTi1.1Al0.2共晶高熵合金在不同温度退火热处理下的微观结构和力学性能演变规律。研究结果表明,铸态V0.3CoCr1.2NiTi1.1Al0.2中存在由FCC相和BCC相耦合生长的不规则共晶组织和两相非耦合生长的晶界区域,且晶界区的FCC基体相中含有球状BCC结构析出相和针状HCP结构Ti(Ni,Co)3析出相。500 ℃热处理细化了晶界区域的两种纳米析出相;700 ℃热处理会略微粗化纳米析出相;900 ℃热处理在进一步粗化析出相的基础上还会粗化晶界区域;1100℃热处理会同时粗化共晶组织、晶界区域和纳米析出相。细小纳米析出相的弥散分布以及其他相的稳定性促使500 ℃处理的合金展现出最优的压缩强度和压缩应变;热处理温度升高会带来合金微观结构的粗化效果,从而恶化其力学性能。

       

      Abstract: The evolution of microstructure and mechanical properties of V0.3CoCr1.2NiTi1.1Al0.2 eutectic high entropy alloy (EHEA) subjected to annealing heat treatments at different temperatures was investigated. The results reveal that the as cast V0.3CoCr1.2NiTi1.1Al0.2 EHEA exhibits irregular eutectic colonies with coupled growth of FCC and BCC phases and grain boundary region with two-phase non-coupled growth. In the grain boundary regions, the FCC matrix phase contains spherical BCC precipitates and needle-like HCP Ti(Ni,Co)3 precipitates. Annealing at 500 ℃ refines the two types of nano- precipitates at the grain boundaries. Annealing at 700 ℃ results in slight coarsening of the nano-precipitates. Annealing at 900 ℃ further coarsens the precipitates and furthermore coarsens the grain boundary areas. Annealing at 1100 ℃ simultaneously coarsens the eutectic colonies, the grain boundary regions and the nano-precipitates. The fine nano-precipitates with a dispersed distribution combined with the stability of the other phases are attributed to the optimal compressive strength and compressive strain of the alloy annealed at 500 ℃. Increasing the annealing temperature promotes microstructure coarsening, which consequently leads to the deterioration of the mechanical properties.

       

    /

    返回文章
    返回