陕北某含硫采油井抽油杆失效分析及治理对策研究

    Failure Analysis and Countermeasures of Sucker Rods in a Sulfur-containing Oil Well in Northern Shaanxi

    • 摘要: 陕北某含硫采油井抽油杆腐蚀严重,服役1年左右就会发生断裂。对断裂抽油杆进行宏观形貌分析,利用SEM、EDS和XRD进行腐蚀特征分析,结合抽油杆服役工况分析抽油杆失效原因,同时通过现场腐蚀速率检测、腐蚀产物膜表征和抗拉性能测试,优选了适用于该油井的抽油杆材质。结果表明:失效的3130合金钢抽油杆的化学成分符合标准要求,抽油杆表面有大量腐蚀坑,平均腐蚀速率为1.6986 mm/a,最大点蚀深度为3.5 mm。腐蚀产物主要为FeCO3、Fe7S8和CaCO3,造成抽油杆断裂的主要原因是高矿化度含硫采出水引起的CO2/H2S腐蚀,高含Cl-也会促进点蚀发展。3种抽油杆材质的耐蚀性依次为4330A合金钢>25CrMoA合金钢>3130合金钢。腐蚀187 d后,4330A合金钢和25CrMoA合金钢表面平整,抗拉性能能够达到D级抽油杆标准。建议现场采用耐蚀性较好的4330A合金钢抽油杆。

       

      Abstract: The sucker rod of a sulfur-containing oil well in northern Shaanxi is seriously corroded, and it will break after service for about 1 year. The macroscopic morphology of the fractured sucker rod was analyzed, and the corrosion characteristics were analyzed by SEM, EDS and XRD. The failure reason of the sucker rod was determined by combining the service conditions of the sucker rod. At the same time, the sucker rod material suitable for the oil well was optimized by on-site corrosion rate detection, corrosion product film characterization and tensile performance test. The results show that the chemical composition of the failed 3130 alloy steel sucker rod meets the standard, there are a large number of corrosion pits on the surface of the sucker rod. The average corrosion rate is about 1.6986 mm/a, and the maximum pitting depth is 3.5 mm. The corrosion products are mainly FeCO3, Fe7S8 and CaCO3. The main reason for the fracture of the sucker rod is CO2/H2S corrosion caused by high salinity sulfur-containing produced water. High Cl- content will also promote the development of pitting corrosion. The corrosion resistance of the three sucker rod materials is 4330A alloy steel>25CrMoA alloy steel> 3130 alloy steel. After 187 days of corrosion, the surface of 4330A alloy steel and 25CrMoA alloy steel is flat, and the tensile performance can reach the D-class sucker rod standard. It is recommended to use 4330A alloy steel sucker rod with good corrosion resistance on site.

       

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