GH6783高温合金螺栓在超超临界机组中的断裂特征与机理研究

    Investigation on Fracture Characteristics and Mechanisms of GH6783 Superalloy Bolts in Ultra-supercritical Units

    • 摘要: 针对某1000 MW超超临界机组服役近30000 h发生断裂的GH6783高温合金螺栓,采用宏观形貌观察、力学性能测试、热膨胀性能测定、金相分析、X射线衍射(XRD)、扫描电镜(SEM)及能谱分析(EDS)等手段,系统开展断裂特征、失效诱因与断裂机理研究。结果表明:长时高温服役后螺栓本体拉伸、硬度指标仍满足标准要求,但冲击韧性、断后伸长率显著下降;合金表面抗氧化能力不足,螺纹根部形成大量点蚀坑,点蚀区域形成由铁氧化物外层、多元合金氧化物中间层、含针片状脆性析出相的退化基体内层组成的梯度缺陷结构;材料晶界β-NiAl相粗化并形成连续沿晶网络,β相内部析出硬脆针状Ni5Al3相,加剧材料脆化。机组启停带来的低周交变载荷促使疲劳裂纹优先在螺牙根部点蚀缺陷处萌生并向内扩展。在表面氧化诱导疲劳开裂与应力加速晶界氧化(stress accelerated grain boundary oxidation,SAGBO)脆化的协同作用下,螺栓有效承载截面不断缩减,最终发生宏观脆性断裂。本研究可为超超临界机组同类高温合金紧固件失效预防、安全评估提供理论依据与工程参考。

       

      Abstract: A systematic investigation into the fracture characteristics, contributing factors and fracture mechanism was carried out for fractured GH6783 superalloy bolts which had served for nearly 30000 h in a 1000 MW ultra supercritical unit. Techniques including macroscopic morphology observation, mechanical property test, thermal expansion measurement, metallographic analysis, X ray diffraction(XRD), scanning electron microscopy(SEM) and energy dispersive spectroscopy (EDS) were adopted. The results show that although the tensile properties, hardness of the bolt matrix still meet the standard requirements after long term high temperature service, its impact toughness and percentage reduction of area decrease significantly. The alloy exhibits insufficient surface oxidation resistance, and numerous pitting pits are formed at the thread roots. A gradient defect structure is generated in the pitting zone, consisting of an outer iron oxide layer, an intermediate multi alloy oxide layer and an inner degraded matrix layer containing acicular plate shaped brittle precipitates. The grain boundary β-NiAl phase coarsens and forms a continuous intergranular network, and hard brittle acicular Ni5Al3 phase precipitates inside the β phase, further aggravating material embrittlement. Low cycle alternating loads induced by unit start up and shut down promote fatigue cracks to preferentially initiate at pitting defects on thread roots and propagate inwards. Under the synergistic effect of surface oxidation induced fatigue cracking and SAGBO (stress accelerated grain boundary oxidation) embrittle-ment, the effective load bearing cross section of the bolt shrinks continuously, and macroscopic brittle fracture occurs eventually. This study provides theoretical basis and engineering reference for failure prevention and safety assessment of similar superalloy fasteners used in ultra supercritical units.

       

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